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HomeMy WebLinkAboutINS-13-024 - Region and City of Waterloo Drinking Water 2012 Summary REPORT TO: Community & Infrastructure Services Committee DATE OF MEETING: March 18, 2013 SUBMITTED BY: Jim Witmer, Interim Deputy CAO, Infrastructure Services, 741-2600 x 4657 PREPARED BY: Angela Mick, P.Eng. Utilities Water Engineer, 741-2600 X 4408 WARD(S) INVOLVED: All DATE OF REPORT: March 5, 2013 REPORT NO.: INS 13-024 SUBJECT: Region of Waterloo Drinking Water 2012 Summary Report and the City of Waterloo Drinking Water 2012 Summary Report RECOMMENDATION: THAT the 2012 City of Waterloo Drinking Water Summary Report be received for information as required by O.Reg170/03 Schedule 22 of the Safe Drinking Water Act, THAT the six 2012 Region of Waterloo Annual Water Quality Reports (Strange St. Well Supply System, Well K34, Mannheim Water Treatment Plant and Pumping Station, Greenbrook Well Supply System, Woolners Well Supply and the Parkway Well Supply System) be received for information as required by O.Reg170/03 Schedule 22 of the Safe Drinking Water Act, BACKGROUND: As outlined in Schedule 22 of the Drinking Water Systems Regulation (O.Reg.170/03) of the Safe Drinking Water Act, 2002, a summary report is to be prepared and given to the members of the municipal council. The following information is required to be included in this report: “ (a) list the requirements of the Act, the regulations, the system’s approval and any order that the system failed to meet at any time during the period covered by the report and specify the duration of the failures; and (b) for each failure referred to in (a), describe the measures that were taken to correct the failure.” The report must also include: 3 - 1 “1. A summary of the quantities and flow rates of the water supplied during the period covered by the report….” REPORT: Please see attached reports. ALIGNMENT WITH CITY OF KITCHENER STRATEGIC PLAN: The Annual Summary Water Report relates to the Foundation Plan – Efficient and Effective Government – Communications goal to “Proactively communicate with Kitchener residents in an effort to share information; educate and engage the public, and promote enterprises, programs and services; to create a corporate culture where internal communications is a priority for all City” FINANCIAL IMPLICATIONS: N/A COMMUNITY ENGAGEMENT: Under Schedule 22 of O.Reg. 170/03, municipalities are required to provide a copy of their Summary Report to each Municipality to which it supplies water. Reports are also available to the public on the individual municipalities websites. ACKNOWLEDGED BY: Jim Witmer, Interim Deputy CAO, Infrastructure Services 3 - 2 3 - 3 3 - 4 3 - 5 3 - 6 Drinking-Water Systems Regulation O. Reg. 170/03 ANNUAL REPORT Drinking-Water System Number: 220003092 Drinking-Water System Name: Kitchener Water Supply System: Strange St. Well Supply System Drinking-Water System Owner: Region of Waterloo Drinking-Water System Category: Large Municipal Residential Period being reported: January 1 to December 31, 2012 Complete if your Category is Large Municipal Complete for all other Categories. Residential or Small Municipal Residential Does your Drinking-Water System serve Number of Designated Facilities served: more than 10,000 people? Yes [x] No [ ] Is your annual report available to the public Did you provide a copy of your annual at no charge on a web site on the Internet? report to all Designated Facilities you Yes [x] No [ ]serve? Yes [ ] No [ ] Location where Summary Report required under O. Reg. 170/03 Schedule 22 will be Number of Interested Authorities you available for inspection. report to: On-line at: Did you provide a copy of your annual http://www.region.waterloo.on.ca/water report to all Interested Authorities you report to for each Designated Facility? or contact Mr. Peter Clarke at: Yes [ ] No [ ] (519)-575-4757 ext. 3155 Note: For the following tables below, additional rows or columns may be added or an appendix may be attached to the report List all Drinking-Water Systems (if any), which receive all of their drinking water from your system: Drinking Water System Name Drinking Water System Number Kitchener Distribution System 260001458 Did you provide a copy of your annual report to all Drinking-Water System owners that are connected to you and to whom you provide all of its drinking water? Yes [x] No [ ] Drinking Water Systems Regulations Page 1of 5 (PIBS 4435e01) 3 - 7 Drinking-Water Systems Regulation O. Reg. 170/03 Indicate how you notified system users that your annual report is available, and is free of charge. [x] Public access/notice via the web [ ] Public access/notice via Government Office [x] Public access/notice via a newspaper [x] Public access/notice via Public Request [ ] Public access/notice via a Public Library [ ] Public access/notice via other method _______________________________________ Describe your Drinking-Water System The Strange Street Well System is comprised of five ground water wells, K10A, K11A, K13, K18 and K19. These wells pump directly into the Strange Street Reservoir and Pumping Station. The Strange Street Reservoir has a capacity of 940,000 imperial gallons (4.27 ML). The water is disinfected prior to entering the reservoir. Disinfection is achieved by the use of sodium hypochlorite systems consisting of solution tanks complete with spill containment and protection and metering pumps dispensing commercial 12% sodium hypochlorite solution, located at wells K10A, K11A, K13 and K18/K19 prior to entering the reservoir. Ammonium sulphate is added to the water at the discharge header of the pumping station prior to the water leaving the station. The purpose of the ammonium sulphate is to convert the free chlorine residual to a combined chlorine residual. Continuous analyzers monitor the levels of chlorine and turbidity prior to the water being discharged. The analyzers are connected with the Mannheim Water Treatment Plant SCADA system which is monitored by an operator 24 hours per day. This site has no emergency standby power available on site. List all water treatment chemicals used over this reporting period 12% Sodium Hypochlorite, 20% Ammonium Sulphate Were any significant expenses incurred to? [ ] Install required equipment [ ] Repair required equipment [X] Replace required equipment Please provide a brief description and a breakdown of monetary expenses incurred Approximately 540 metres of 450 mm raw watermain was installed to replace an existing 300 mm raw watermain. Approximate cost $560,000. Drinking Water Systems Regulations Page 2of 5 (PIBS 4435e01) 3 - 8 Drinking-Water Systems Regulation O. Reg. 170/03 Provide details on the notices submitted in accordance with subsection 18(1) of the Safe Drinking-Water Act or section 16-4 of Schedule 16 of O.Reg.170/03 and reported to Spills Action Centre Incident Date Parameter Result Unit of Corrective Action Corrective Measure Action Date March 6/12 Chloramines 3.00 mg/L Resampled March 7/12 *Result was from a short term on-line analyzer spike Adverse Water Quality Incidents for Regional locations not directly related to treated entry points (eg. Water Towers, Distribution Facilities etc.) can be located at www.region.waterloo.on.ca by referencing the Region of Waterloo 2011 Summary Report, Appendix B. Microbiological testing done under the Schedule 10, 11 or 12 of Regulation 170/03, during this reporting period. Number Range of Range of Total Number Range of HPC of E.Coli Or Fecal Coliform of HPC Results Samples Results Results Samples (min #)-(max #) (min #)-(max #) (min #)-(max #) Raw (p/a) 156* All absent All absent Not required Raw (MF) 1 0 - 0 0 - 0 Treated 54 All absent All absent 54 0 - 9 Distribution Two-tier system; distribution system operated by City of Kitchener *Well K11A was offline for 52 weeks, well K18 was offline for 49 weeks, and well K19 was offline for 5 weeks in 2012. Operational testing done under Schedule 7, 8 or 9 of Regulation 170/03 during the period covered by this Annual Report. Number ofRange of Results NOTE : For continuous Grab (min #)-(max #) monitors use 8760 as the Samples number of samples. Turbidity (Raw)36 0.14 – 1.66 NTU Chlorine (Total)8760 0.57 – 3.00 Fluoride (If the DWS provides DWS does not provide fluoridation fluoridation) NOTEnot : Record the unit of measure if it is milligrams per litre. Summary of additional testing and sampling carried out in accordance with the requirement of an approval, order or other legal instrument. Date of legal instrument issued Parameter Date Result Unit of Measure Sampled Not applicable; no additional testing or sampling required. Summary of Inorganic parameters tested during this reporting period or the most recent sample results Parameter Sample Date Result Value Unit of Measure Exceedance Antimony 2/29/12 <0.6 ug/L No Arsenic 2/29/12 <1 ug/L No Barium 2/29/12 0.133 mg/L No Boron 2/29/12 0.013 mg/L No Drinking Water Systems Regulations Page 3of 5 (PIBS 4435e01) 3 - 9 Drinking-Water Systems Regulation O. Reg. 170/03 Cadmium 2/29/12 <0.1 ug/L No Chromium 2/29/12 <0.001 mg/L No Mercury 2/29/12 <0.05 ug/L No Selenium 2/29/12 <5.0 ug/L No Sodium 4/16/08 85.9 mg/L No* Uranium 2/29/12 <0.01 mg/L No Fluoride 7/11/12 <0.05 mg/L No 1/03/12 <0.075 mg/L No 4/10/12 <0.015 mg/L No Nitrite 7/11/12 <0.015 mg/L No 10/17/12 <0.015 mg/L No 1/03/12 0.64 mg/L No 4/10/12 0.60 mg/L No Nitrate 7/11/12 0.55 mg/L No 10/17/12 0.58 mg/L No * There no health related limit set for sodium, however, levels of greater than 20 mg/L are reported to the Health Department and the Ministry of Environment every five years. Summary of Organic parameters sampled during this reporting period or the most recent sample results Parameter Sample Result Unit of Exceedance Date Value Measure Alachlor 2/29/12 <0.13 ug/L No Aldicarb 2/29/12<0.5 ug/L No Aldrin + Dieldrin 2/29/12<0.07 ug/L No Atrazine + N-dealkylated metobolites 2/29/12<0.38 ug/L No Azinphos-methyl 2/29/12<1.0 ug/L No Bendiocarb 2/29/12<0.2 ug/L No Benzene 2/29/12<0.5 ug/L No Benzo(a)pyrene 2/29/12<0.01 ug/L No Bromoxynil 2/29/12<0.05 ug/L No Carbaryl 2/29/12<0.2 ug/L No Carbofuran 2/29/12<0.2 ug/L No Carbon Tetrachloride 2/29/12<0.5 ug/L No Chlordane (Total) 2/29/12<0.39 ug/L No Chlorpyrifos 2/29/12<0.25 ug/L No Cyanazine 2/29/12<0.25 ug/L No Diazinon 2/29/12<0.13 ug/L No Dicamba 2/29/12<0.5 ug/L No 1,2-Dichlorobenzene 2/29/12<0.5 ug/L No 1,4-Dichlorobenzene 2/29/12<0.5 ug/L No Dichlorodiphenyltrichloroethane (DDT) + 2/29/12 <0.78 ug/L No metabolites 1,2-Dichloroethane 2/29/12<0.5 ug/L No 1,1-Dichloroethylene 2/29/12 <0.5 ug/L No (vinylidene chloride) Dichloromethane 2/29/12<1.0 ug/L No 2-4 Dichlorophenol 2/29/12<0.13 ug/L No 2,4-Dichlorophenoxy acetic acid (2,4-D) 2/29/12<0.5 ug/L No Diclofop-methyl2/29/12<0.5 ug/L No Dimethoate 2/29/12<0.25 ug/L No Dinoseb 2/29/12<0.5 ug/L No Drinking Water Systems Regulations Page 4of 5 (PIBS 4435e01) 3 - 10 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Sample Result Unit of Exceedance Date Value Measure Diquat 2/29/12<1.0 ug/L No Diuron 2/29/12<0.6 ug/L No Glyphosate 2/29/12<25 ug/L No Heptachlor + Heptachlor Epoxide 2/29/12<0.26 ug/L No Lindane (Total) 2/29/12<0.13 ug/L No Malathion 2/29/12<0.13 ug/L No Methoxychlor 2/29/12<0.13 ug/L No Metolachlor 2/29/12<0.25 ug/L No Metribuzin 2/29/12<0.13 ug/L No Monochlorobenzene 2/29/12<0.5 ug/L No Paraquat 2/29/12<1.0 ug/L No Parathion 2/29/12<1.25 ug/L No Pentachlorophenol 2/29/12<0.13 ug/L No Phorate 2/29/12<0.25 ug/L No Picloram 2/29/12<1.5 ug/L No Polychlorinated Biphenyls(PCB) 2/29/12<0.25 ug/L No Prometryne 2/29/12<0.25 ug/L No Simazine 2/29/12<0.13 ug/L No THMTwo-tier system; distribution system operated by City (NOTE: show latest annual average)of Kitchener Temephos 2/29/12<2.5 ug/L No Terbufos 2/29/12<0.25 ug/L No Tetrachloroethylene 2/29/12<0.5 ug/L No 2,3,4,6-Tetrachlorophenol 2/29/12<0.13 ug/L No Triallate 2/29/12<0.2 ug/L No Trichloroethylene 2/29/12<0.5 ug/L No 2,4,6-Trichlorophenol 2/29/12<0.13 ug/L No 2,4,5-Trichlorophenoxy acetic acid (2,4,5-T) 2/29/12<0.5 ug/L No Trifluralin 2/29/12<0.25 ug/L No Vinyl Chloride 2/29/12<0.2 ug/L No List any Inorganic or Organic parameter(s) that exceeded half the standard prescribed in Schedule 2 of Ontario Drinking Water Quality Standards. Parameter Result Value Unit of Measure Date of Sample Chloramines mg/L 1.54 1/03/12 Chloramines mg/L 3.00 3/06/12 Chloramines mg/L 1.57 3/27/12 Chloramines mg/L 1.54 4/03/12 Chloramines mg/L 1.59 4/17/12 Chloramines mg/L 1.81 7/05/12 Chloramines mg/L 1.75 7/05/12 Chloramines mg/L 1.54 7/18/12 Chloramines mg/L 1.85 7/25/12 Drinking Water Systems Regulations Page 5of 5 (PIBS 4435e01) 3 - 11 Drinking-Water Systems Regulation O. Reg. 170/03 ANNUAL REPORT Drinking-Water System Number: 220003092 Drinking-Water System Name: Kitchener Water Supply System: Well K34 Drinking-Water System Owner: Region of Waterloo Drinking-Water System Category: Large Municipal Residential Period being reported: January 1 to December 31, 2012 Complete if your Category is Large Municipal Complete for all other Categories. Residential or Small Municipal Residential Does your Drinking-Water System serve Number of Designated Facilities served: more than 10,000 people? Yes [x] No [ ] Is your annual report available to the public Did you provide a copy of your annual at no charge on a web site on the Internet? report to all Designated Facilities you Yes [x] No [ ]serve? Yes [ ] No [ ] Location where Summary Report required under O. Reg. 170/03 Schedule 22 will be Number of Interested Authorities you available for inspection. report to: On-line at: Did you provide a copy of your annual http://www.region.waterloo.on.ca/water report to all Interested Authorities you report to for each Designated Facility? or contact Mr. Peter Clarke at: Yes [ ] No [ ] (519)-575-4757 ext. 3155 Note: For the following tables below, additional rows or columns may be added or an appendix may be attached to the report List all Drinking-Water Systems (if any), which receive all of their drinking water from your system: Drinking Water System Name Drinking Water System Number Kitchener Distribution System 260001458 Did you provide a copy of your annual report to all Drinking-Water System owners that are connected to you and to whom you provide all of its drinking water? Yes [x] No [ ] Drinking Water Systems Regulations Page 1of 6 (PIBS 4435e01) 3 - 12 Drinking-Water Systems Regulation O. Reg. 170/03 Indicate how you notified system users that your annual report is available, and is free of charge. [x] Public access/notice via the web [ ] Public access/notice via Government Office [x] Public access/notice via a newspaper [x] Public access/notice via Public Request [ ] Public access/notice via a Public Library [ ] Public access/notice via other method _______________________________________ Describe your Drinking-Water System The K34 water supply is a groundwater supply consisting of two wells, K34 and K36, a treatment facility and an in ground clear well/reservoir. The total storage capacity of the reservoir is 90 cubic meters. Two high lift pumps are used to discharge the treated water into the distribution system. The treatment facility has five closed pressure filters used for removal of iron and manganese. Disinfection is achieved by the use of a sodium hypochlorite system consisting of a solution tank complete with spill containment and protection and two metering pumps dispensing commercial 12% sodium hypochlorite solution. The sodium hypochlorite is also used as an oxidizing agent prior to filtration. Upon discharge to the distribution system, 20% ammonium sulphate is injected; which converts free chlorine to a more stable combined chlorine. Continuous analyzers monitor the levels of chlorine and turbidity. The analyzers are connected with the Mannheim Water Treatment Plant SCADA system which is monitored by an operator 24 hours per day. There is no emergency stand-by electrical power at this facility. List all water treatment chemicals used over this reporting period 12% Sodium Hypochlorite, 20% Ammonium Sulphate Were any significant expenses incurred to? [ ] Install required equipment [ ] Repair required equipment [ ] Replace required equipment Please provide a brief description and a breakdown of monetary expenses incurred Not applicable; no significant expenses incurred. Drinking Water Systems Regulations Page 2of 6 (PIBS 4435e01) 3 - 13 Drinking-Water Systems Regulation O. Reg. 170/03 Provide details on the notices submitted in accordance with subsection 18(1) of the Safe Drinking-Water Act or section 16-4 of Schedule 16 of O.Reg.170/03 and reported to Spills Action Centre Incident Date Parameter Result Unit of Corrective Action Corrective Measure Action Date April 5/12 Chloramines* 3.1 mg/L Resampled April 5/12 August 5/12 Chloramines* 3.05 mg/LResampled and flushed mains August 5/12 September 1/12 Chloramines* 3.3 mg/L Resampled and flushed mains September 1/12 *Results are from short term on-line analyzer spikes Adverse Water Quality Incidents for Regional locations not directly related to treated entry points (eg. Water Towers, Distribution Facilities etc.) can be located at www.region.waterloo.on.ca by referencing the Region of Waterloo 2011 Summary Report, Appendix B. Microbiological testing done under the Schedule 10, 11 or 12 of Regulation 170/03, during this reporting period. Number Range of E.Coli Range of Total Number Range of HPC of Or Fecal Coliform of HPC Results Samples Results Results Samples (min #)-(max #) (min #)-(max #) (min #)-(max #) Raw 58* All absent All absent Not required Treated 28 All absent All absent 28 0 - 2 Distribution Two-tier system; distribution system operated by City of Kitchener *Wells K34 and K36 were offline for 25 weeks in 2012. Operational testing done under Schedule 7, 8 or 9 of Regulation 170/03 during the period covered by this Annual Report. Number of Range of Results NOTE : For continuous Grab (min #)-(max #) monitors use 8760 as the Samples number of samples. Turbidity (Raw)14 0.11 – 2.16 NTU Chlorine (Total)8760 0.89 – 3.30 Fluoride (If the DWS provides DWS does not provide fluoridation fluoridation) NOTEnot : Record the unit of measure if it is milligrams per litre. Summary of additional testing and sampling carried out in accordance with the requirement of an approval, order or other legal instrument. Date of legal instrument Parameter Date Sampled Result Unit of Measure issued Not applicable; no additional testing or sampling required. Drinking Water Systems Regulations Page 3of 6 (PIBS 4435e01) 3 - 14 Drinking-Water Systems Regulation O. Reg. 170/03 Summary of Inorganic parameters tested during this reporting period or the most recent sample results Parameter Sample Date Result Value Unit of Measure Exceedance Antimony 4/11/12<0.6 ug/L No Arsenic 4/11/12<1.0 ug/L No Barium 4/11/120.101 mg/L No Boron 4/11/120.026 mg/L No Cadmium 4/11/12<0.1 ug/L No Chromium 4/11/12<0.001 mg/L No Mercury 4/11/12<0.05 ug/L No Selenium 4/11/12<5.0 ug/L No Sodium 8/15/11 44.8 mg/L No* Uranium 4/11/12 <0.01 mg/L No Fluoride 7/24/12 0.28 mg/L No 4/04/12 <0.015 mg/L No 7/09/12 <0.015 mg/L No Nitrite 7/24/12 <0.015 mg/L No 10/09/12 <0.015 mg/L No 4/04/12 <0.10 mg/L No 7/09/12 <0.10 mg/L No Nitrate 7/24/12 <0.10 mg/L No 10/09/12 <0.10 mg/L No * There is no health related limit set for sodium, however, levels of greater than 20 mg/L are reported to the Health Department and the Ministry of Environment every five years. Summary of lead testing under Schedule 15.1 during this reporting period Range of Lead Number of Number of Location Type Results SamplesExceedances (min#) – (max #) Plumbing Two-tier system; distribution system operated by City of Kitchener Distribution Summary of Organic parameters sampled during this reporting period or the most recent sample results Parameter Sample Result Unit of Exceedance Date Value Measure Alachlor 4/11/12 <0.13 ug/L No Aldicarb 4/11/12 <0.5 ug/L No Aldrin + Dieldrin 4/11/12 <0.07 ug/L No Atrazine + N-dealkylated metobolites 4/11/12 <0.38 ug/L No Azinphos-methyl 4/11/12 <1.0 ug/L No Bendiocarb 4/11/12 <0.2 ug/L No Benzene 4/11/12 <0.5 ug/L No Benzo(a)pyrene 4/11/12 <0.01 ug/L No Bromoxynil 4/11/12 <0.05 ug/L No Carbaryl 4/11/12 <0.2 ug/L No Carbofuran 4/11/12 <0.2 ug/L No Carbon Tetrachloride 4/11/12 <0.5 ug/L No Chlordane (Total) 4/11/12 <0.39 ug/L No Chlorpyrifos 4/11/12 <0.25 ug/L No Cyanazine 4/11/12 <0.25 ug/L No Drinking Water Systems Regulations Page 4of 6 (PIBS 4435e01) 3 - 15 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Sample Result Unit of Exceedance Date Value Measure Diazinon 4/11/12 <0.13 ug/L No Dicamba 4/11/12 <0.5 ug/L No 1,2-Dichlorobenzene 4/11/12 <0.5 ug/L No 1,4-Dichlorobenzene 4/11/12 <0.5 ug/L No Dichlorodiphenyltrichloroethane (DDT) + 4/11/12 <0.78 ug/L No metabolites 1,2-Dichloroethane 4/11/12 <0.5 ug/L No 1,1-Dichloroethylene 4/11/12 <0.5 ug/L No (vinylidene chloride) Dichloromethane 4/11/12 <1.0 ug/L No 2-4 Dichlorophenol 4/11/12 <0.13 ug/L No 2,4-Dichlorophenoxy acetic acid (2,4-D) 4/11/12 <0.5 ug/L No Diclofop-methyl4/11/12 <0.5 ug/L No Dimethoate 4/11/12 <0.25 ug/L No Dinoseb 4/11/12 <0.5 ug/L No Diquat 4/11/12 <1.0 ug/L No Diuron 4/11/12 <0.6 ug/L No Glyphosate 4/11/12 <25 ug/L No Heptachlor + Heptachlor Epoxide 4/11/12 <0.26 ug/L No Lindane (Total) 4/11/12 <0.13 ug/L No Malathion 4/11/12 <0.13 ug/L No Methoxychlor 4/11/12 <0.13 ug/L No Metolachlor 4/11/12 <0.25 ug/L No Metribuzin 4/11/12 <0.13 ug/L No Monochlorobenzene 4/11/12 <0.5 ug/L No Paraquat 4/11/12 <1.0 ug/L No Parathion 4/11/12 <1.25 ug/L No Pentachlorophenol 4/11/12 <0.13 ug/L No Phorate 4/11/12 <0.25 ug/L No Picloram 4/11/12 <1.5 ug/L No Polychlorinated Biphenyls(PCB) 4/11/12 <0.25 ug/L No Prometryne 4/11/12 <0.25 ug/L No Simazine 4/11/12 <0.13 ug/L No THM Two-tier system; distribution system operated by City (NOTE: show latest annual average) of Kitchener Temephos 4/11/12 <2.5 ug/L No Terbufos 4/11/12 <0.25 ug/L No Tetrachloroethylene 4/11/12 <0.5 ug/L No 2,3,4,6-Tetrachlorophenol 4/11/12 <0.13 ug/L No Triallate 4/11/12 <0.2 ug/L No Trichloroethylene 4/11/12 <0.5 ug/L No 2,4,6-Trichlorophenol 4/11/12 <0.13 ug/L No 2,4,5-Trichlorophenoxy acetic acid (2,4,5-T) 4/11/12 <0.5 ug/L No Trifluralin 4/11/12 <0.25 ug/L No Vinyl Chloride 4/11/12 <0.2 ug/L No Drinking Water Systems Regulations Page 5of 6 (PIBS 4435e01) 3 - 16 Drinking-Water Systems Regulation O. Reg. 170/03 List any Inorganic or Organic parameter(s) that exceeded half the standard prescribed in Schedule 2 of Ontario Drinking Water Quality Standards. Parameter Result Value Unit of Measure Date of Sample Chloramines3.10 mg/L 4/05/12 Chloramines1.51 mg/L 4/11/12 Chloramines1.54 mg/L 4/16/12 Chloramines1.74 mg/L 5/08/12 Chloramines1.52 mg/L 5/16/12 Chloramines1.54 mg/L 5/28/12 Chloramines1.56 mg/L 6/11/12 Chloramines1.57 mg/L 6/25/12 Chloramines1.61 mg/L 7/09/12 Chloramines1.56 mg/L 7/16/12 Chloramines1.68 mg/L 7/24/12 Chloramines3.05 mg/L 8/05/12 Chloramines1.70 mg/L 8/14/12 Chloramines1.65 mg/L 8/20/12 Chloramines 1.60 mg/L 8/28/12 Chloramines3.30 mg/L 9/01/12 Chloramines 1.56 mg/L 9/24/12 Drinking Water Systems Regulations Page 6of 6 (PIBS 4435e01) 3 - 17 Drinking-Water Systems Regulation O. Reg. 170/03 ANNUAL REPORT Drinking-Water System Number: 220006981 Drinking-Water System Name: Kitchener Water Supply System: Mannheim Water Treatment Plant and Pumping Station Drinking-Water System Owner: Region of Waterloo Drinking-Water System Category: Large Municipal Residential Period being reported: January 1 to December 31, 2012 Complete if your Category is Large Municipal Complete for all other Categories. Residential or Small Municipal Residential Does your Drinking-Water System serve Number of Designated Facilities served: more than 10,000 people? Yes [x] No [ ] Is your annual report available to the public Did you provide a copy of your annual at no charge on a web site on the Internet? report to all Designated Facilities you Yes [x] No [ ]serve? Yes [ ] No [ ] Location where Summary Report required under O. Reg. 170/03 Schedule 22 will be Number of Interested Authorities you available for inspection. report to: On-line at: Did you provide a copy of your annual http://www.region.waterloo.on.ca/water report to all Interested Authorities you report to for each Designated Facility? or contact Mr. Peter Clarke at: Yes [ ] No [ ] (519)-575-4757 ext. 3155 Note: For the following tables below, additional rows or columns may be added or an appendix may be attached to the report List all Drinking-Water Systems (if any), which receive all of their drinking water from your system: Drinking Water System Name Drinking Water System Number Kitchener Distribution System 260001458 Did you provide a copy of your annual report to all Drinking-Water System owners that are connected to you and to whom you provide all of its drinking water? Yes [x] No [ ] Drinking Water Systems Regulations Page 1of 13 (PIBS 4435e01) 3 - 18 Drinking-Water Systems Regulation O. Reg. 170/03 Indicate how you notified system users that your annual report is available, and is free of charge. [x] Public access/notice via the web [ ] Public access/notice via Government Office [x] Public access/notice via a newspaper [x] Public access/notice via Public Request [ ] Public access/notice via a Public Library [ ] Public access/notice via other method _______________________________________ Describe your Drinking-Water System The Mannheim Water Treatment Plant receives raw water from the Hidden Valley Low Lift Station located at the Grand River. The raw water entering the WTP is treated with coagulation, flocculation, sedimentation, ozonation and filtration. Immediately after filtration, the water is disinfected prior to entering the clearwells/reservoirs. There are two clearwells/reservoirs that have a combined total usable volume of 15.28 ML. Disinfection is achieved through ozonation, ultraviolet (UV) irradiation followed by chlorination via a gas chlorination system. Continuous analyzers monitor the levels of ozone, chlorine, turbidity and UV prior to the water being discharged. The analyzers are connected with the Mannheim Water Treatment Plant SCADA system which is monitored by an operator 24 hours per day. The water from the Mannheim Aquifer Storage and Recovery Facilities (ASR1, ASR2, ASR3, ASR4, RCW1 and RCW2) can be mixed with the treated water and then stored in the clearwells/reservoirs. This water is then directed to the Mannheim Pumping Station Reservoir, where it blends with seven other ground water wells (K91, K92, K93, K94, K21, K25, and K29). Treated water from the Mannheim Village wells (K22A, K23, K24 and K26) can also indirectly supply the Mannheim Pumping Station Reservoir. This reservoir has a total storage capacity of 122.7 ML. Prior to the treated water being pumped into the distribution system, annhydrous ammonia is injected to convert free chlorine to the combined form, creating a more stable distribution disinfectant. As a backup to the anhydrous ammonia system, there is also the capability to inject 20% liquid ammonium sulphate. This facility has emergency standby power available. List all water treatment chemicals used over this reporting period Chlorine gas, 12% sodium hypochlorite, anhydrous ammonia, polyaluminum chloride (coagulant), polyelectrolyte (filter aid), liquid oxygen (LOX), ozone, ultraviolet (UV) irradiation, calcium thiosulphate, granular activated carbon, 20% ammonium sulphate. Drinking Water Systems Regulations Page 2of 13 (PIBS 4435e01) 3 - 19 Drinking-Water Systems Regulation O. Reg. 170/03 Were any significant expenses incurred to? [X] Install required equipment [X] Repair required equipment [X] Replace required equipment Please provide a brief description and a breakdown of monetary expenses incurred Network Communication at Aquifer Storage and Recovery wells upgraded. Approximate cost $70,000. Dry chlorine scrubber installed. Approximate cost $180,000. SCADA network upgraded. Approximate cost $415,000. Provide details on the notices submitted in accordance with subsection 18(1) of the Safe Drinking-Water Act or section 16-4 of Schedule 16 of O.Reg.170/03 and reported to Spills Action Centre IncidentParameter Result Unit of Corrective Action Corrective Date Measure Action Date No adverse results during the 2012 reporting period. Adverse Water Quality Incidents for Regional locations not directly related to treated entry points (eg. Water Towers, Distribution Facilities etc.) can be located at www.region.waterloo.on.ca by referencing the Region of Waterloo 2011 Summary Report, Appendix B. Microbiological testing done under the Schedule 10, 11 or 12 of Regulation 170/03, during this reporting period. Number Range of E.Coli Range of Total Number Range of HPC of Or Fecal Coliform of HPC Results Samples Results Results Samples (min #)-(max #) (min #)-(max #) (min #)-(max #) Raw (wells) p/a 666* 1 detection 22 detections Not required Raw (wells) MF 26 0-1 0-2 Raw (surface 313 0 – 5300 10 – >59,000 Not required water) MF Treated 56 All absent All absent 56 0 - 4 Distribution Two-tier system; distribution system operated by City of Kitchener *Well K21 was offline for 19 weeks, ASR3 was offline for 1 week, RCW1 was offline for 3 weeks, RCW2 was offline for 2 weeks, K94 was offline for 6 weeks, K93 was offline for 3 weeks and K92 was offline for 1 week in 2012. Operational testing done under Schedule 7, 8 or 9 of Regulation 170/03 during the period covered by this Annual Report. Number of Range of Results NOTE : For continuous Grab (min #)-(max #) monitors use 8760 as the Samples number of samples. Turbidity (Raw) 304 <0.10 – 10.29 NTU Turbidity (post 0.017 – 1.396*NTU 8760 filter) (*1 minute spike) Chlorine (Total) 8760 0.45 – 2.00 Fluoride (If the DWS provides DWS does not provide fluoridation. fluoridation) NOTEnot : Record the unit of measure if it is milligrams per litre. Drinking Water Systems Regulations Page 3of 13 (PIBS 4435e01) 3 - 20 Drinking-Water Systems Regulation O. Reg. 170/03 Summary of additional testing and sampling carried out in accordance with the requirement of an approval, order or other legal instrument. Date of legal Date Parameter Result Unit of Measure instrument issued Sampled Bromide 1/10/12 0.044 mg/L Municipal Drinking Bromide 2/10/12 0.046 mg/L Water Licence 012- Bromide 3/20/12 0.036 mg/L 102 issued June 18, Bromide 4/17/12 0.066 mg/L 2012 requires monthly Bromide 5/14/12 0.069 mg/L sampling for Bromide Bromide 6/05/12 0.079 mg/L at point of entrance to Bromide 7/16/12 0.051 mg/L treatment plant (raw Bromide 8/15/12 0.059 mg/L water). Bromide 9/20/12 0.082 mg/L Bromide 10/18/12 0.053 mg/L Bromide 11/15/12 0.067 mg/L Bromide 12/13/12 0.066 mg/L Bromate 1/10/12 <0.003 mg/L Municipal Drinking Bromate 2/10/12 <0.003 mg/L Water Licence 012- Bromate 3/20/12 <0.003 mg/L 102 issued June 18, Bromate 4/17/12 0.004 mg/L 2012 requires monthly Bromate 5/14/12 <0.003 mg/L sampling for Bromate Bromate 6/05/12 <0.003 mg/L at Mannheim Bromate 7/16/12 <0.003 mg/L Reservoir Pumping Bromate 8/15/12 <0.003 mg/L Station Discharge. Bromate 9/20/12 <0.003 mg/L Bromate 10/18/12 <0.003mg/L Bromate11/15/12 <0.003mg/L Bromate12/13/12 <0.003mg/L Municipal Drinking Water Licence 012- 102 issued June 18, 2012 requires Not applicable - Water from the treated reservoir was not injected into the ASR continuous sampling recharge wells in 2012. for free chlorine on water injected into ASR recharge wells (when water is from the treated reservoir). Chloramines (mono/di) 1/12/12 1.15 0.44 mg/L Municipal Drinking Chloramines (mono/di) 1/18/12 0.75 0.52 mg/L Water Licence 012- Chloramines (mono/di) 1/19/12 1.12 0.39 mg/L 102 issued June 18, Chloramines (mono/di) 1/25/12 1.32 0.40 mg/L 2012 requires monthly Chloramines (mono/di) 2/01/12 1.26 0.41 mg/L sampling for Chloramines (mono/di) 2/08/12 1.22 0.49 mg/L chloramines at the Chloramines (mono/di) 2/14/12 1.40 0.34 mg/L Mannheim Reservoir Chloramines (mono/di) 2/21/12 1.22 0.39 mg/L Pumping Station Chloramines (mono/di) 2/27/12 1.48 0.32 mg/L Discharge Chloramines (mono/di) 2/27/12 1.46 0.32 mg/L Chloramines (mono/di) 3/06/12 1.40 0.36 mg/L Chloramines (mono/di) 3/20/12 0.98 0.54 mg/L Chloramines (mono/di) 3/27/12 1.32 0.26 mg/L Drinking Water Systems Regulations Page 4of 13 (PIBS 4435e01) 3 - 21 Drinking-Water Systems Regulation O. Reg. 170/03 Date of legal Date Parameter Result Unit of Measure instrument issued Sampled Chloramines (mono/di) 4/03/12 1.35 0.29 mg/L Municipal Drinking Chloramines (mono/di) 4/10/12 1.35 0.29 mg/L Water Licence 012- Chloramines (mono/di) 4/08/12 1.28 0.36 mg/L 102 issued June 18, Chloramines (mono/di) 4/26/12 1.13 0.34 mg/L 2012 requires monthly Chloramines (mono/di) 5/18/12 1.50 0.24 mg/L sampling for Chloramines (mono/di) 5/23/12 1.45 0.30 mg/L chloramines at the Chloramines (mono/di) 5/30/12 1.09 0.29 mg/L Mannheim Reservoir Chloramines (mono/di) 6/06/12 1.30 0.26 mg/L Pumping Station Chloramines (mono/di) 6/13/12 1.11 0.32 mg/L Discharge Chloramines (mono/di) 6/20/12 1.11 0.25 mg/L Chloramines (mono/di) 6/28/12 1.25 0.22 mg/L Chloramines (mono/di) 7/03/12 1.00 0.24 mg/L Chloramines (mono/di) 7/12/12 1.11 0.22 mg/L Chloramines (mono/di) 7/18/12 1.10 0.18 mg/L Chloramines (mono/di) 7/25/12 1.21 0.19 mg/L Chloramines (mono/di) 8/01/12 1.09 0.23 mg/L Chloramines (mono/di) 8/09/12 1.28 0.20 mg/L Chloramines (mono/di) 8/15/12 1.47 0.16 mg/L Chloramines (mono/di) 8/22/12 1.40 0.25 mg/L Chloramines (mono/di) 8/29/12 1.10 0.20 mg/L Chloramines (mono/di) 9/05/12 1.20 0.27 mg/L Chloramines (mono/di) 9/12/12 1.28 0.22 mg/L Chloramines (mono/di) 9/26/12 1.47 0.28 mg/L Chloramines (mono/di) 10/03/12 1.19 0.32 mg/L Chloramines (mono/di) 10/11/12 1.41 0.31 mg/L Chloramines (mono/di) 10/17/12 1.38 0.33 mg/L Chloramines (mono/di) 10/25/12 1.36 0.32 mg/L Chloramines (mono/di) 10/31/12 1.25 0.29 mg/L Chloramines (mono/di) 11/06/12 1.39 0.21 mg/L Chloramines (mono/di) 11/14/12 1.27 0.34 mg/L Chloramines (mono/di) 11/22/12 1.33 0.35 mg/L Chloramines (mono/di) 11/28/12 1.31 0.32 mg/L Chloramines (mono/di) 12/05/12 1.34 0.38 mg/L Chloramines (mono/di) 12/12/12 1.39 0.32 mg/L Chloramines (mono/di) 12/20/12 1.28 0.34 mg/L Chloramines (mono/di) 12/27/12 1.42 0.34 mg/L Summary of Inorganic parameters tested during this reporting period or the most recent sample results Parameter Sample Date Result Value Unit of Measure Exceedance Antimony 1/19/12 <0.6 ug/L No 4/19/12 <0.6ug/L No 7/16/12 <0.6 ug/L No 10/18/12 <0.6ug/L No Arsenic 1/19/12 <1.0ug/L No 4/19/12 <1.0ug/L No 7/16/12 <1.0 ug/L No 10/18/12 <1.0ug/L No Drinking Water Systems Regulations Page 5of 13 (PIBS 4435e01) 3 - 22 Drinking-Water Systems Regulation O. Reg. 170/03 Barium 1/19/12 0.062 mg/L No 4/19/12 0.072 mg/L No 7/16/12 0.071 mg/L No 10/18/12 0.060 mg/L No Boron 1/19/12 <0.010 mg/L No 4/19/12 0.020 mg/L No 7/16/12 0.017 mg/L No 10/18/12 <0.050 mg/L No Cadmium 1/19/12 <0.1ug/L No 4/19/12 <0.1ug/L No 7/16/12 <0.1 ug/L No 10/18/12 <0.1ug/L No Chromium 1/19/12 <0.001 mg/L No 4/19/12 <0.001 mg/L No 7/16/12 <0.001 mg/L No 10/18/12 <0.001 mg/L No 12/04/12 <0.001 mg/L No Mercury 1/19/12 <0.05 ug/L No 4/19/12 <0.05 ug/L No 7/16/12 <0.05 ug/L No 10/18/12 <0.05 ug/L No Selenium 1/19/12 <5.0 ug/L No 4/19/12 <5.0 ug/L No 7/16/12 <5.0 ug/L No 10/18/12 <5.0 ug/L No Sodium 6/11/08 37.2 mg/L No* Uranium 1/19/12 <0.01 mg/L No 4/19/12 <0.01 mg/L No 7/16/12 <0.005 mg/L No 10/18/12 <0.005 mg/L No Fluoride 1/10/12 <0.05 mg/L No 2/10/12 0.10 mg/L No 3/20/12 0.08 mg/L No 4/17/12 0.09 mg/L No 5/14/12 0.06 mg/L No 6/05/12 0.15 mg/L No 7/16/12 0.06 mg/L No 8/15/12 0.12 mg/L No 9/20/12 0.11 mg/L No 10/18/12 0.05 mg/L No 11/15/12 <0.05 mg/L No 12/13/12 0.10 mg/L No 1/10/12 <0.015 mg/L No 1/19/12 <0.015 mg/L No 2/10/12 <0.015 mg/L No 3/20/12 <0.015mg/L No Nitrite 4/17/12 <0.015mg/L No 4/19/12 <0.015mg/L No 5/14/12 <0.015mg/L No 6/05/12 <0.015mg/L No 7/16/12 <0.015mg/L No 8/15/12 <0.015mg/L No Drinking Water Systems Regulations Page 6of 13 (PIBS 4435e01) 3 - 23 Drinking-Water Systems Regulation O. Reg. 170/03 9/20/12 <0.015mg/L No 10/18/12 <0.015mg/L No 10/18/12 <0.015mg/L No 11/15/12 <0.015mg/L No 12/04/12 <0.015mg/L No 12/13/12 <0.015mg/L No 1/10/12 4.75 mg/L No 1/19/12 5.00 mg/L No 2/10/12 4.20 mg/L No 3/20/12 3.86 mg/L No 4/17/12 3.59 mg/L No 4/19/12 3.90 mg/L No 5/14/12 2.98 mg/L No 6/05/12 3.00 mg/L No Nitrate 7/16/12 2.90 mg/L No 8/15/12 2.52 mg/L No 9/20/12 2.87 mg/L No 10/18/12 2.97 mg/L No 10/18/12 2.93 mg/L No 11/15/12 4.00 mg/L No 12/04/12 4.17 mg/L No 12/13/12 4.30 mg/L No * There is no health related limit set for sodium, however, levels of greater than 20 mg/L are reported to the Health Department and the Ministry of Environment every five years. Summary of lead testing under Schedule 15.1 during this reporting period Range of Lead Number of Number of Location Type Results SamplesExceedances (min#) – (max #) Plumbing Two-tier system; distribution system operated by City of Kitchener Distribution Summary of Organic parameters sampled during this reporting period or the most recent sample results Parameter Sample Result Unit of Exceedance Date Value Measure Alachlor 1/19/12 <0.13ug/L No 4/19/12 <0.13ug/L No 7/16/12 <0.13ug/L No 10/18/12 <0.13ug/L No Aldicarb1/19/12 <0.5ug/L No 4/19/12 <0.5ug/L No 7/16/12 <0.5ug/L No 10/18/12 <0.5 ug/L No Aldrin + Dieldrin 1/19/12 <0.07 ug/L No 4/19/12 <0.07ug/L No 7/16/12 <0.07ug/L No 10/18/12 <0.07ug/L No Atrazine + N-dealkylated metobolites 1/19/12 <0.38ug/L No Drinking Water Systems Regulations Page 7of 13 (PIBS 4435e01) 3 - 24 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Sample Result Unit of Exceedance Date Value Measure 4/19/12 <0.38ug/L No 7/16/12 <0.38ug/L No 10/18/12 <0.38ug/L No Azinphos-methyl 1/19/12 <1.0ug/L No 4/19/12 <1.0ug/L No 7/16/12 <1.0ug/L No 10/18/12 <1.0ug/L No Bendiocarb 1/19/12 <0.2ug/L No 4/19/12 <0.2ug/L No 7/16/12 <0.2ug/L No 10/18/12 <0.2ug/L No Benzene 1/19/12 <0.5 ug/L No 4/19/12 <0.5 ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No Benzo(a)pyrene 1/19/12 <0.01 ug/L No 4/19/12 <0.01 ug/L No 7/16/12 <0.01 ug/L No 10/18/12 <0.01 ug/L No Bromoxynil 1/19/12 <0.05ug/L No 4/19/12 <0.05ug/L No 7/16/12 <0.05ug/L No 10/18/12 <0.05ug/L No Carbaryl 1/19/12 <0.2ug/L No 4/19/12 <0.2ug/L No 7/16/12 <0.2ug/L No 10/18/12 <0.2ug/L No Carbofuran 1/19/12 <0.2ug/L No 4/19/12 <0.2ug/L No 7/16/12 <0.2ug/L No 10/18/12 <0.2ug/L No Carbon Tetrachloride 1/19/12 <0.5 ug/L No 4/19/12 <0.5 ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No Chlordane (Total) 1/19/12 <0.39ug/L No 4/19/12 <0.39ug/L No 7/16/12 <0.39 ug/L No 10/18/12 <0.39ug/L No Chlorpyrifos 1/19/12 <0.25ug/L No 4/19/12 <0.25ug/L No 7/16/12 <0.25ug/L No 10/18/12 <0.25ug/L No Cyanazine 1/19/12 <0.25ug/L No 4/19/12 <0.25ug/L No 7/16/12 <0.25ug/L No 10/18/12 <0.25ug/L No Diazinon 1/19/12 <0.13ug/L No 4/19/12 <0.13ug/L No 7/16/12 <0.13 ug/L No Drinking Water Systems Regulations Page 8of 13 (PIBS 4435e01) 3 - 25 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Sample Result Unit of Exceedance Date Value Measure 10/18/12 <0.13 ug/L No Dicamba 1/19/12 <0.5ug/L No 4/19/12 <0.5ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No 1,2-Dichlorobenzene 1/19/12 <0.5 ug/L No 4/19/12 <0.5 ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No 1,4-Dichlorobenzene 1/19/12 <0.5 ug/L No 4/19/12 <0.5 ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No Dichlorodiphenyltrichloroethane (DDT) + 1/19/12 <0.78ug/L No metabolites 4/19/12 <0.78ug/L No 7/16/12 <0.78 ug/L No 10/18/12 <0.78 ug/L No 1,2-Dichloroethane 1/19/12 <0.5 ug/L No 4/19/12 <0.5 ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No 1,1-Dichloroethylene 1/19/12 <0.5 ug/L No (vinylidene chloride) 4/19/12 <0.5 ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No Dichloromethane 1/19/12 <1.0 ug/L No 4/19/12 <1.0 ug/L No 7/16/12 <1.0 ug/L No 10/18/12 <1.0 ug/L No 2-4 Dichlorophenol 1/19/12 <0.13 ug/L No 4/19/12 <0.13ug/L No 7/16/12 <1.3ug/L No 10/18/12 <1.3 ug/L No 2,4-Dichlorophenoxy acetic acid (2,4-D) 1/19/12 <0.5ug/L No 4/19/12 <0.5ug/L No 7/16/12 <0.5ug/L No 10/18/12 <0.5 ug/L No Diclofop-methyl1/19/12 <0.5ug/L No 4/19/12 <0.5ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No Dimethoate 1/19/12 <0.25 ug/L No 4/19/12 <0.25ug/L No 7/16/12 <0.25ug/L No 10/18/12 <0.25ug/L No Dinoseb 1/19/12 <0.5ug/L No 4/19/12 <0.5ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No Diquat 1/19/12 <1.0ug/L No Drinking Water Systems Regulations Page 9of 13 (PIBS 4435e01) 3 - 26 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Sample Result Unit of Exceedance Date Value Measure 4/19/12 <1.0ug/L No 7/16/12 <1.0ug/L No 10/18/12 <1.0ug/L No Diuron 1/19/12 <0.6ug/L No 4/19/12 <0.6ug/L No 7/16/12 <0.6ug/L No 10/18/12 <0.6 ug/L No Glyphosate 1/19/12 <25.0ug/L No 4/19/12 <25.0ug/L No 7/16/12 <25.0ug/L No 10/18/12 <25.0ug/L No Heptachlor + Heptachlor Epoxide 1/19/12 <0.26ug/L No 4/19/12 <0.26ug/L No 7/16/12 <0.26ug/L No 10/18/12 <0.26ug/L No Lindane (Total) 1/19/12 <0.13 ug/L No 4/19/12 <0.13 ug/L No 7/16/12 <0.13ug/L No 10/18/12 <0.13 ug/L No Malathion 1/19/12 <0.13ug/L No 4/19/12 <0.13ug/L No 7/16/12 <1.3 ug/L No 10/18/12 <1.3ug/L No Methoxychlor 1/19/12 <0.13ug/L No 4/19/12 <0.13ug/L No 7/16/12 <0.13ug/L No 10/18/12 <0.13 ug/L No Metolachlor 1/19/12 <0.25ug/L No 4/19/12 <0.25ug/L No 7/16/12 <0.25ug/L No 10/18/12 <0.25ug/L No Metribuzin 1/19/12 <0.13 ug/L No 4/19/12 <0.13 ug/L No 7/16/12 <0.13 ug/L No 10/18/12 <0.13 ug/L No Monochlorobenzene 1/19/12 <0.5 ug/L No 4/19/12 <0.5 ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No Paraquat 1/19/12 <1.0 ug/L No 4/19/12 <1.0 ug/L No 7/16/12 <1.0 ug/L No 10/18/12 <1.0 ug/L No Parathion 1/19/12 <1.25ug/L No 4/19/12 <1.25ug/L No 7/16/12 <1.25ug/L No 10/18/12 <1.25 ug/L No Pentachlorophenol 1/19/12 <0.13ug/L No 4/19/12 <0.13ug/L No 7/16/12 <1.3ug/L No Drinking Water Systems Regulations Page 10of 13 (PIBS 4435e01) 3 - 27 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Sample Result Unit of Exceedance Date Value Measure 10/18/12 <1.3ug/L No Phorate 1/19/12 <0.25ug/L No 4/19/12 <0.25ug/L No 7/16/12 <0.25ug/L No 10/18/12 <0.25ug/L No Picloram 1/19/12 <1.5ug/L No 4/19/12 <1.5ug/L No 7/16/12 <1.5ug/L No 10/18/12 <1.5ug/L No Polychlorinated Biphenyls(PCB) 1/19/12 <0.25ug/L No 4/19/12 <0.25ug/L No 7/16/12 <0.25ug/L No 10/18/12 <0.25ug/L No Prometryne 1/19/12 <0.25ug/L No 4/19/12 <0.25ug/L No 7/16/12 <0.25ug/L No 10/18/12 <0.25ug/L No Simazine 1/19/12 <0.13ug/L No 4/19/12 <0.13ug/L No 7/16/12 <0.13 ug/L No 10/18/12 <0.13 ug/L No THM1/03/12 12.7 ug/L No THM2/07/12 12.5 ug/L No THM3/06/12 11.8 ug/L No THM4/03/12 15.4 ug/L No THM4/10/12 17.1 ug/L No THM5/01/12 16.2 ug/L No THM6/06/12 26.3 ug/L No THM7/03/12 35.9 ug/L No THM8/07/12 43.6 ug/L No THM9/05/12 37.5 ug/L No THM10/02/12 24.8 ug/L No THM11/06/12 22.8 ug/L No THM12/04/12 17.8 ug/L No THM 26.7 ug/L No NOTE: show latest annual average () Temephos 1/19/12 <2.5ug/L No 4/19/12 <2.5ug/L No 7/16/12 <2.5ug/L No 10/18/12 <2.5ug/L No Terbufos 1/19/12 <0.25ug/L No 4/19/12 <0.25ug/L No 7/16/12 <0.25ug/L No 10/18/12 <0.25ug/L No Tetrachloroethylene 1/19/12 <0.5 ug/L No 4/19/12 <0.5 ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No 2,3,4,6-Tetrachlorophenol 1/19/12 <0.13ug/L No 4/19/12 <0.13ug/L No Drinking Water Systems Regulations Page 11of 13 (PIBS 4435e01) 3 - 28 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Sample Result Unit of Exceedance Date Value Measure 7/16/12 <1.3ug/L No 10/18/12 <1.3ug/L No Triallate 1/19/12 <0.2ug/L No 4/19/12 <0.2ug/L No 7/16/12 <0.2ug/L No 10/18/12 <0.2 ug/L No Trichloroethylene 1/19/12 <0.5 ug/L No 4/19/12 <0.5 ug/L No 7/16/12 <0.5 ug/L No 10/18/12 <0.5 ug/L No 2,4,6-Trichlorophenol 1/19/12 <0.13ug/L No 4/19/12 <0.13ug/L No 7/16/12 <0.13ug/L No 10/18/12 <0.25ug/L No 2,4,5-Trichlorophenoxy acetic acid (2,4,5-T) 1/19/12 <0.5ug/L No 4/19/12 <0.5ug/L No 7/16/12 <0.5ug/L No 10/18/12 <0.5 ug/L No Trifluralin 1/19/12 <0.25ug/L No 4/19/12 <0.25ug/L No 7/16/12 <0.25ug/L No 10/18/12 <0.25ug/L No Vinyl Chloride 1/19/12 <0.2 ug/L No 4/19/12 <0.2 ug/L No 7/16/12 <0.2 ug/L No 10/18/12 <0.2 ug/L No List any Inorganic or Organic parameter(s) that exceeded half the standard prescribed in Schedule 2 of Ontario Drinking Water Quality Standards. Parameter Result Value Unit of Measure Date of Sample Chloramines 1.59 mg/L 1/12/12 Chloramines 1.51 mg/L 1/19/12 Chloramines 1.63 mg/L 1/24/12 Chloramines 1.72 mg/L1/25/12 Chloramines 1.60 mg/L1/31/12 Chloramines 1.67 mg/L2/01/12 Chloramines 1.71 mg/L2/08/12 Chloramines 1.74 mg/L2/14/12 Chloramines 1.61 mg/L2/21/12 Chloramines 1.80 mg/L2/27/12 Chloramines 1.78 mg/L2/27/12 Chloramines 1.58 mg/L2/28/12 Chloramines 1.51 mg/L3/06/12 Chloramines 1.76 mg/L3/06/12 Chloramines 1.52 mg/L3/20/12 Chloramines 1.58 mg/L3/27/12 Chloramines 1.64 mg/L4/03/12 Chloramines 1.64 mg/L4/08/12 Drinking Water Systems Regulations Page 12of 13 (PIBS 4435e01) 3 - 29 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Result Value Unit of Measure Date of Sample Chloramines 1.64 mg/L4/10/12 Chloramines 1.60 mg/L 4/10/12 Chloramines 1.53 mg/L 5/01/12 Chloramines1.74 mg/L5/18/12 Chloramines1.60 mg/L5/22/12 Chloramines1.75 mg/L5/23/12 Chloramines1.38 mg/L5/30/12 Chloramines1.56 mg/L6/06/12 Chloramines1.73 mg/L8/15/12 Chloramines1.58 mg/L8/15/12 Chloramines1.65 mg/L8/22/12 Chloramines1.68 mg/L8/23/12 Chloramines1.55 mg/L9/20/12 Chloramines1.75 mg/L9/26/12 Chloramines1.58 mg/L9/27/12 Chloramines1.51 mg/L10/03/12 Chloramines1.58 mg/L10/04/12 Chloramines1.65 mg/L10/11/12 Chloramines1.72 mg/L10/11/12 Chloramines1.71 mg/L10/17/12 Chloramines1.68 mg/L10/25/12 Chloramines1.62 mg/L10/25/12 Chloramines1.54 mg/L10/31/12 Chloramines1.60 mg/L11/06/12 Chloramines1.61 mg/L11/14/12 Chloramines1.68 mg/L11/22/12 Chloramines1.63 mg/L11/28/12 Chloramines1.72 mg/L12/05/12 Chloramines1.61 mg/L12/05/12 Chloramines1.71 mg/L12/12/12 Chloramines1.55 mg/L12/13/12 Chloramines1.62 mg/L12/20/12 Chloramines1.76 mg/L12/27/12 Chloramines1.63 mg/L12/27/12 Drinking Water Systems Regulations Page 13of 13 (PIBS 4435e01) 3 - 30 Drinking-Water Systems Regulation O. Reg. 170/03 ANNUAL REPORT Drinking-Water System Number: 220003092 Drinking-Water System Name: Kitchener Water Supply System: Greenbrook Well Supply System Drinking-Water System Owner: Region of Waterloo Drinking-Water System Category: Large Municipal Residential Period being reported: January 1 to December 31, 2012 Complete if your Category is Large Municipal Complete for all other Categories. Residential or Small Municipal Residential Does your Drinking-Water System serve Number of Designated Facilities served: more than 10,000 people? Yes [x] No [ ] Is your annual report available to the public Did you provide a copy of your annual at no charge on a web site on the Internet? report to all Designated Facilities you Yes [x] No [ ]serve? Yes [ ] No [ ] Location where Summary Report required under O. Reg. 170/03 Schedule 22 will be Number of Interested Authorities you available for inspection. report to: On-line at: Did you provide a copy of your annual http://www.region.waterloo.on.ca/water report to all Interested Authorities you report to for each Designated Facility? or contact Mr. Peter Clarke at: Yes [ ] No [ ] (519)-575-4757 ext. 3155 Note: For the following tables below, additional rows or columns may be added or an appendix may be attached to the report List all Drinking-Water Systems (if any), which receive all of their drinking water from your system: Drinking Water System Name Drinking Water System Number Kitchener Distribution System 260001458 Did you provide a copy of your annual report to all Drinking-Water System owners that are connected to you and to whom you provide all of its drinking water? Yes [x] No [ ] Drinking Water Systems Regulations Page 1of 5 (PIBS 4435e01) 3 - 31 Drinking-Water Systems Regulation O. Reg. 170/03 Indicate how you notified system users that your annual report is available, and is free of charge. [x] Public access/notice via the web [ ] Public access/notice via Government Office [x] Public access/notice via a newspaper [x] Public access/notice via Public Request [ ] Public access/notice via a Public Library [ ] Public access/notice via other method _______________________________________ Describe your Drinking-Water System The Greenbrook Well System is comprised of five ground water wells K1, K2, K4B, K5A and K8. These wells pump directly into the Greenbrook Treatment Plant and Pumping Station. Iron and manganese removal is achieved through the use of three pressure filters. Following filtration, treatment for 1,4-dioxane is accomplished by an advanced oxidation process using 50% hydrogen peroxide and Ultraviolet (UV) irradiation. Treated water from the UV reactors proceeds through upflow Granular Activated Carbon (GAC) contactors before being transferred to 2 storage reservoirs with capacities of 2 million gallons (approximately 10,000 cubic metres) and 500,000 gallons (approximately 2400 cubic metres). Disinfection is achieved through Ultraviolet (UV) irradiation and by the use of a sodium hypochlorite system consisting of a solution tank complete with spill containment and protection and a metering pump dispensing commercial 12% sodium hypochlorite solution. 20% ammonium sulphate is added to the water at the discharge header of the pumping station prior to the water leaving the station. The purpose of the ammonium sulphate is to convert free chlorine to the combined form, creating a more stable distribution disinfectant. Continuous analyzers monitor the levels of chlorine, turbidity and UV prior to the water being discharged. The analyzers are connected with the Mannheim Water Treatment Plant SCADA system which is monitored by an operator 24 hours per day. There is no emergency standby power at this site. List all water treatment chemicals used over this reporting period 12% Sodium Hypochlorite, 20% Ammonium Sulphate , 50% Hydrogen Peroxide Were any significant expenses incurred to? [ ] Install required equipment [ ] Repair required equipment [ ] Replace required equipment Please provide a brief description and a breakdown of monetary expenses incurred Not applicable; no significant expenses incurred. Drinking Water Systems Regulations Page 2of 5 (PIBS 4435e01) 3 - 32 Drinking-Water Systems Regulation O. Reg. 170/03 Provide details on the notices submitted in accordance with subsection 18(1) of the Safe Drinking-Water Act or section 16-4 of Schedule 16 of O.Reg.170/03 and reported to Spills Action Centre Incident Date Parameter Result Unit of Corrective Action Corrective Measure Action Date No adverse results during the 2012 reporting period. Adverse Water Quality Incidents for Regional locations not directly related to treated entry points (eg. Water Towers, Distribution Facilities etc.) can be located at www.region.waterloo.on.ca by referencing the Region of Waterloo 2011 Summary Report, Appendix B. Microbiological testing done under the Schedule 10, 11 or 12 of Regulation 170/03, during this reporting period. Number Range of E.Coli Range of Total Number Range of HPC of Or Fecal Coliform of HPC Results Samples Results Results Samples (min #)-(max #) (min #)-(max #) (min #)-(max #) Raw 250 All Absent 1 detection Not required Treated55 All Absent All Absent 55 0 - 32 Distribution Two-tier system; distribution system operated by the City of Kitchener *Wells K1, K2, K4B, K5A and K8 were offline for 4 weeks in 2012. Operational testing done under Schedule 7, 8 or 9 of Regulation 170/03 during the period covered by this Annual Report. Number of Range of Results NOTE : For continuous Grab (min #)-(max #) monitors use 8760 as the Samples number of samples. Turbidity (Raw)60 0.1 – 7.7 NTU Turbidity (online –post 0.027 – 4.27* NTU 8760 filter -Pre UV) (*1 minute spike) Chlorine (Total)8760 0.64 – 2.13 Fluoride (If the DWS DWS does not provide fluoridation provides fluoridation) NOTEnot : Record the unit of measure if it is milligrams per litre. Summary of additional testing and sampling carried out in accordance with the requirement of an approval, order or other legal instrument. Date of legal instrument Parameter Date Sampled Result Unit of Measure issued Not applicable; no additional testing or sampling required. Summary of Inorganic parameters tested during this reporting period or the most recent sample results Parameter Sample Date Result Value Unit of Measure Exceedance Antimony 7/16/12 <0.6 ug/L No Arsenic 7/16/12 <1.0 ug/L No Barium 7/16/12 0.077 mg/L No Boron 7/16/12 0.022 mg/L No Cadmium 7/16/12 <0.1 ug/L No Drinking Water Systems Regulations Page 3of 5 (PIBS 4435e01) 3 - 33 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Sample Date Result Value Unit of Measure Exceedance Chromium 7/16/12 <0.001 mg/L No Mercury 7/16/12 <0.05 ug/L No Selenium 7/16/12 <5.0 ug/L No Sodium 9/09/08 112 mg/L No* Uranium 7/16/12 <0.005 mg/L No Fluoride 10/17/12 0.11 mg/L No 1/05/12 <0.075 mg/L No 4/10/12 <0.015 mg/L No Nitrite 7/11/12 <0.015 mg/L No 10/17/12 <0.015 mg/L No 10/17/12 <0.015 mg/L No 1/05/12 3.26 mg/L No 4/10/12 3.19 mg/L No Nitrate 7/11/12 2.69 mg/L No 10/17/12 2.90 mg/L No 10/17/12 2.91 mg/L No * There is no health related limit set for sodium, however, levels of greater than 20 mg/L are reported to the Health Department and the Ministry of Environment every five years. Summary of lead testing under Schedule 15.1 during this reporting period Range of Lead Number of Number of Location Type Results SamplesExceedances (min#) – (max #) Plumbing Two-tier system; distribution system operated by City of Kitchener Distribution Summary of Organic parameters sampled during this reporting period or the most recent sample results Parameter Sample Date ResultUnit of Exceedance Value Measure Alachlor 7/16/12 <0.13 ug/L No Aldicarb7/16/12<0.5 ug/L No Aldrin + Dieldrin 7/16/12<0.07 ug/L No Atrazine + N-dealkylated metobolites 7/16/12<0.38 ug/L No Azinphos-methyl 7/16/12<1.0 ug/L No Bendiocarb 7/16/12<0.2 ug/L No Benzene 7/16/12<0.5 ug/L No Benzo(a)pyrene 7/16/12<0.01 ug/L No Bromoxynil 7/16/12<0.05 ug/L No Carbaryl 7/16/12<0.2 ug/L No Carbofuran 7/16/12<0.2 ug/L No Carbon Tetrachloride 7/16/12<0.5 ug/L No Chlordane (Total) 7/16/12<0.39 ug/L No Chlorpyrifos 7/16/12<0.25 ug/L No Cyanazine 7/16/12<0.25 ug/L No Diazinon 7/16/12<0.13 ug/L No Dicamba 7/16/12<0.5 ug/L No 1,2-Dichlorobenzene 7/16/12<0.5 ug/L No 1,4-Dichlorobenzene 7/16/12<0.5 ug/L No Drinking Water Systems Regulations Page 4of 5 (PIBS 4435e01) 3 - 34 Drinking-Water Systems Regulation O. Reg. 170/03 Dichlorodiphenyltrichloroethane 7/16/12 <0.78 ug/L No (DDT) + metabolites 1,2-Dichloroethane 7/16/12<0.5 ug/L No 1,1-Dichloroethylene 7/16/12 <0.5 ug/L No (vinylidene chloride) Dichloromethane 7/16/12<1.0 ug/L No 2-4 Dichlorophenol 7/16/12<1.3 ug/L No 2,4-Dichlorophenoxy acetic acid (2,4-D) 7/16/12<0.5 ug/L No Diclofop-methyl7/16/12<0.5 ug/L No Dimethoate 7/16/12<0.25 ug/L No Dinoseb 7/16/12<0.5 ug/L No Diquat 7/16/12<1.0 ug/L No Diuron 7/16/12<0.6 ug/L No Glyphosate 7/16/12<25 ug/L No Heptachlor + Heptachlor Epoxide 7/16/12<0.26 ug/L No Lindane (Total) 7/16/12<0.13 ug/L No Malathion 7/16/12<1.3 ug/L No Methoxychlor 7/16/12<0.13 ug/L No Metolachlor 7/16/12<0.25 ug/L No Metribuzin 7/16/12<0.13 ug/L No Monochlorobenzene 7/16/12<0.5 ug/L No Paraquat 7/16/12<1.0 ug/L No Parathion 7/16/12<1.25 ug/L No Pentachlorophenol 7/16/12<1.3 ug/L No Phorate 7/16/12<0.25 ug/L No Picloram 7/16/12<1.5 ug/L No Polychlorinated Biphenyls(PCB) 7/16/12<0.25 ug/L No Prometryne 7/16/12<0.25 ug/L No Simazine 7/16/12<0.13 ug/L No THMTwo-tier system; distribution system operated by City of (NOTE: show latest annual average) Kitchener Temephos 7/16/12<2.5 ug/L No Terbufos 7/16/12<0.25 ug/L No Tetrachloroethylene 7/16/12<0.5 ug/L No 2,3,4,6-Tetrachlorophenol 7/16/12<1.3 ug/L No Triallate 7/16/12<0.2 ug/L No Trichloroethylene 7/16/12<0.5 ug/L No 2,4,6-Trichlorophenol 7/16/12<0.13 ug/L No 2,4,5-Trichlorophenoxy acetic acid 7/16/12 <0.5 ug/L No (2,4,5-T) Trifluralin 7/16/12<0.25 ug/L No Vinyl Chloride 7/16/12<0.2 ug/L No List any Inorganic or Organic parameter(s) that exceeded half the standard prescribed in Schedule 2 of Ontario Drinking Water Quality Standards. Parameter Result Value Unit of Measure Date of Sample Not applicable; no schedule 2 half standards exceeded. Drinking Water Systems Regulations Page 5of 5 (PIBS 4435e01) 3 - 35 Drinking-Water Systems Regulation O. Reg. 170/03 ANNUAL REPORT Drinking-Water System Number: 220003092 Drinking-Water System Name: Kitchener Water Supply System: Woolners Well Supply Drinking-Water System Owner: Region of Waterloo Drinking-Water System Category: Large Municipal Residential Period being reported: January 1 to December 31, 2012 Complete if your Category is Large Municipal Complete for all other Categories. Residential or Small Municipal Residential Does your Drinking-Water System serve Number of Designated Facilities served: more than 10,000 people? Yes [x] No [ ] Is your annual report available to the public Did you provide a copy of your annual at no charge on a web site on the Internet? report to all Designated Facilities you Yes [x] No [ ]serve? Yes [ ] No [ ] Location where Summary Report required under O. Reg. 170/03 Schedule 22 will be Number of Interested Authorities you available for inspection. report to: On-line at: Did you provide a copy of your annual http://www.region.waterloo.on.ca/water report to all Interested Authorities you report to for each Designated Facility? or contact Mr. Peter Clarke at: Yes [ ] No [ ] (519)-575-4757 ext. 3155 Note: For the following tables below, additional rows or columns may be added or an appendix may be attached to the report List all Drinking-Water Systems (if any), which receive all of their drinking water from your system: Drinking Water System Name Drinking Water System Number Kitchener Distribution System 260001458 Did you provide a copy of your annual report to all Drinking-Water System owners that are connected to you and to whom you provide all of its drinking water? Yes [x] No [ ] Drinking Water Systems Regulations Page 1of 5 (PIBS 4435e01) 3 - 36 Drinking-Water Systems Regulation O. Reg. 170/03 Indicate how you notified system users that your annual report is available, and is free of charge. [x] Public access/notice via the web [ ] Public access/notice via Government Office [x] Public access/notice via a newspaper [x] Public access/notice via Public Request [ ] Public access/notice via a Public Library [ ] Public access/notice via other method _______________________________________ Describe your Drinking-Water System The Woolners Well Supply system is comprised of three wells: K80, K81, and K82. These wells combine in a common header prior to entering the Ebydale UV Building. The water from the three wells is injected with sodium hypochlorite located in the well houses of K81 and K82. The systems consist of solution tanks complete with spill containment and protection and metering pumps dispensing commercial 12% sodium hypochlorite solution. The water entering the Ebydale UV Building is then passed through an Ultraviolet (UV) system, which provides primary disinfection. Ammonium sulphate is then added to the water at the discharge header prior to the water leaving the station. The purpose of the ammonium sulphate is to convert the free chlorine residual to a more stable combined chlorine residual. Continuous analyzers monitor the levels of chlorine, turbidity and UV prior to the water being discharged. The analyzers are connected with the Mannheim Water Treatment Plant SCADA system which is monitored by an operator 24 hours per day. There is no emergency standby power available at this site. List all water treatment chemicals used over this reporting period Not applicable; system offline all of 2012 Were any significant expenses incurred to? [ ] Install required equipment [ ] Repair required equipment [ ] Replace required equipment Please provide a brief description and a breakdown of monetary expenses incurred Not applicable; no significant expenses incurred. Provide details on the notices submitted in accordance with subsection 18(1) of the Safe Drinking-Water Act or section 16-4 of Schedule 16 of O.Reg.170/03 and reported to Spills Action Centre IncidentParameter Result Unit of Corrective Action Corrective Date Measure Action Date No adverse results during the 2012 reporting period. Adverse Water Quality Incidents for Regional locations not directly related to treated entry points (eg. Water Towers, Distribution Facilities etc.) can be located at www.region.waterloo.on.ca by referencing the Region of Waterloo 2011 Summary Report, Appendix B. Drinking Water Systems Regulations Page 2of 5 (PIBS 4435e01) 3 - 37 Drinking-Water Systems Regulation O. Reg. 170/03 Microbiological testing done under the Schedule 10, 11 or 12 of Regulation 170/03, during this reporting period. Number Range of E.Coli Range of Total Number Range of HPC of Or Fecal Coliform of HPC Results Samples Results Results Samples (min #)-(max #) (min #)-(max #) (min #)-(max #) Raw No microbiological samples were taken in 2012 as this system remained offline for the Treatedentire year Distribution Two-tier system; distribution system operated by City of Kitchener *Ebydale PS was offline for all of 2012. Operational testing done under Schedule 7, 8 or 9 of Regulation 170/03 during the period covered by this Annual Report. Number of Range of Results NOTE : For continuous Grab (min #)-(max #) monitors use 8760 as the Samples number of samples. Turbidity (Raw) Wells were offline all of 2012 Turbidity (online) Chlorine (Total)System was offline all of 2012 Fluoride (If the DWS provides DWS does not provide fluoridation fluoridation) NOTEnot : Record the unit of measure if it is milligrams per litre. Summary of additional testing and sampling carried out in accordance with the requirement of an approval, order or other legal instrument. Date of legal instrument Parameter Date Sampled Result Unit of Measure issued Not applicable; no additional testing or sampling required. Summary of Inorganic parameters tested during this reporting period or the most recent sample results Parameter Sample Date Result Value Unit of Measure Exceedance Antimony 6/10/10 <0.6 ug/L No Arsenic 6/10/10<1.0 ug/L No Barium 6/10/100.020 mg/L No Boron 6/10/10<0.01 mg/L No Cadmium 6/10/10<0.1 ug/L No Chromium 6/10/10<0.001 mg/L No Mercury 6/10/10<0.05 ug/L No Selenium 6/10/10<5.0 ug/L No Sodium 4/27/09 23.6 mg/L No* Uranium 6/10/10 <0.01 mg/L No Fluoride 4/15/10 0.12 mg/L No Nitrite 6/04/10 <0.015mg/L No Nitrate 6/04/10 2.13 mg/L No *There is no health related limit set for sodium, however, levels of greater than 20 mg/L are reported to the Health Department and the Ministry of Environment every five years. Drinking Water Systems Regulations Page 3of 5 (PIBS 4435e01) 3 - 38 Drinking-Water Systems Regulation O. Reg. 170/03 Summary of lead testing under Schedule 15.1 during this reporting period Range of Lead Number of Number of Location Type Results SamplesExceedances (min#) – (max #) Plumbing Two-tier system; distribution system operated by City of Kitchener Distribution Summary of Organic parameters sampled during this reporting period or the most recent sample results Parameter Sample Result Unit of Exceedance Date Value Measure Alachlor 6/10/10 <0.13 ug/L No Aldicarb 6/10/10<0.5 ug/L No Aldrin + Dieldrin 6/10/10<0.07 ug/L No Atrazine + N-dealkylated metobolites 6/10/10<0.38 ug/L No Azinphos-methyl 6/10/10<1.0 ug/L No Bendiocarb 6/10/10<0.2 ug/L No Benzene 6/10/10<0.5 ug/L No Benzo(a)pyrene 6/10/10<0.01 ug/L No Bromoxynil 6/10/10<0.05 ug/L No Carbaryl 6/10/10<0.2 ug/L No Carbofuran 6/10/10<0.2 ug/L No Carbon Tetrachloride 6/10/10<0.5 ug/L No Chlordane (Total) 6/10/10<0.39 ug/L No Chlorpyrifos 6/10/10<0.25 ug/L No Cyanazine 6/10/10<0.25 ug/L No Diazinon 6/10/10<0.13 ug/L No Dicamba 6/10/10<0.5 ug/L No 1,2-Dichlorobenzene 6/10/10<0.5 ug/L No 1,4-Dichlorobenzene 6/10/10<0.5 ug/L No Dichlorodiphenyltrichloroethane (DDT) + 6/10/10<0.78 ug/L No metabolites 1,2-Dichloroethane 6/10/10<0.5 ug/L No 1,1-Dichloroethylene 6/10/10<0.5 ug/L No (vinylidene chloride) Dichloromethane 6/10/10<1.0 ug/L No 2-4 Dichlorophenol 6/10/10<0.13 ug/L No 2,4-Dichlorophenoxy acetic acid (2,4-D) 6/10/10<0.5 ug/L No Diclofop-methyl 6/10/10<0.5 ug/L No Dimethoate 6/10/10<0.25 ug/L No Dinoseb 6/10/10<0.5 ug/L No Diquat 6/10/10<1.0 ug/L No Diuron 6/10/10<0.6 ug/L No Glyphosate 6/10/10<25 ug/L No Heptachlor + Heptachlor Epoxide 6/10/10<0.26 ug/L No Lindane (Total) 6/10/10<0.13 ug/L No Malathion 6/10/10<0.13 ug/L No Methoxychlor 6/10/10<0.13 ug/L No Metolachlor 6/10/10<0.25 ug/L No Metribuzin 6/10/10<0.13 ug/L No Drinking Water Systems Regulations Page 4of 5 (PIBS 4435e01) 3 - 39 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Sample Result Unit of Exceedance Date Value Measure Monochlorobenzene 6/10/10<0.5 ug/L No Paraquat 6/10/10<1.0 ug/L No Parathion 6/10/10<1.25 ug/L No Pentachlorophenol 6/10/10<0.13 ug/L No Phorate 6/10/10<0.25 ug/L No Picloram 6/10/10<1.5 ug/L No Polychlorinated Biphenyls(PCB) 6/10/10<0.25 ug/L No Prometryne 6/10/10<0.25 ug/L No Simazine 6/10/10<0.13 ug/L No THMTwo-tier system; distribution system operated by City (NOTE: show latest annual average) of Kitchener Temephos 6/10/10<2.5 ug/L No Terbufos 6/10/10<0.25 ug/L No Tetrachloroethylene 6/10/10<0.5 ug/L No 2,3,4,6-Tetrachlorophenol 6/10/10<0.13 ug/L No Triallate 6/10/10<0.2 ug/L No Trichloroethylene 6/10/10<0.5 ug/L No 2,4,6-Trichlorophenol 6/10/10<0.13 ug/L No 2,4,5-Trichlorophenoxy acetic acid (2,4,5-T) 6/10/10<0.5 ug/L No Trifluralin 6/10/10<0.25 ug/L No Vinyl Chloride 6/10/10<0.2 ug/L No List any Inorganic or Organic parameter(s) that exceeded half the standard prescribed in Schedule 2 of Ontario Drinking Water Quality Standards. Parameter Result Value Unit of Measure Date of Sample Not applicable; no schedule 2 half standards exceeded in 2012. Drinking Water Systems Regulations Page 5of 5 (PIBS 4435e01) 3 - 40 Drinking-Water Systems Regulation O. Reg. 170/03 ANNUAL REPORT Drinking-Water System Number: 220003092 Drinking-Water System Name: Kitchener Water Supply System: Parkway Well Supply System Drinking-Water System Owner: Region of Waterloo Drinking-Water System Category: Large Municipal Residential Period being reported: January 1 to December 31, 2012 Complete if your Category is Large Municipal Complete for all other Categories. Residential or Small Municipal Residential Does your Drinking-Water System serve Number of Designated Facilities served: more than 10,000 people? Yes [x] No [ ] Is your annual report available to the public Did you provide a copy of your annual at no charge on a web site on the Internet? report to all Designated Facilities you Yes [x] No [ ]serve? Yes [ ] No [ ] Location where Summary Report required under O. Reg. 170/03 Schedule 22 will be Number of Interested Authorities you available for inspection. report to: On-line at: Did you provide a copy of your annual http://www.region.waterloo.on.ca/water report to all Interested Authorities you report to for each Designated Facility? or contact Mr. Peter Clarke at: Yes [ ] No [ ] (519)-575-4757 ext. 3155 Note: For the following tables below, additional rows or columns may be added or an appendix may be attached to the report List all Drinking-Water Systems (if any), which receive all of their drinking water from your system: Drinking Water System Name Drinking Water System Number Kitchener Distribution System 260001458 Did you provide a copy of your annual report to all Drinking-Water System owners that are connected to you and to whom you provide all of its drinking water? Yes [x] No [ ] Drinking Water Systems Regulations Page 1of 6 (PIBS 4435e01) 3 - 41 Drinking-Water Systems Regulation O. Reg. 170/03 Indicate how you notified system users that your annual report is available, and is free of charge. [x] Public access/notice via the web [ ] Public access/notice via Government Office [x] Public access/notice via a newspaper [x] Public access/notice via Public Request [ ] Public access/notice via a Public Library [ ] Public access/notice via other method _______________________________________ Describe your Drinking-Water System The Parkway Well System is comprised of three ground water wells, K31, K32 and K33. These wells pump directly into the Parkway Reservoir and Pumping Station. The Parkway Reservoir has a capacity of three million imperial gallons (14,000 cubic meters). The water is disinfected prior to entering the reservoir. Disinfection is achieved by the use of a sodium hypochlorite system consisting of a solution tank complete with spill containment and protection and a metering pump dispensing commercial 12% sodium hypochlorite solution.Ammonium sulphate is added to the water at the discharge header of the pumping station prior to the water leaving the station. The purpose of the ammonium sulphate is to convert the free chlorine residual to a combined chlorine residual. These chemical systems are located at Parkway Reservoir and Pumping Station. Continuous analyzers monitor the levels of chlorine and turbidity prior to the water being discharged. The analyzers are connected with the Mannheim Water Treatment Plant SCADA system which is monitored by an operator 24 hours per day. This site has no emergency standby power available on site. List all water treatment chemicals used over this reporting period 12% Sodium Hypochlorite, 20% Ammonium Sulphate Were any significant expenses incurred to? [ ] Install required equipment [ ] Repair required equipment [ ] Replace required equipment Please provide a brief description and a breakdown of monetary expenses incurred Not applicable; no significant expenses incurred. Drinking Water Systems Regulations Page 2of 6 (PIBS 4435e01) 3 - 42 Drinking-Water Systems Regulation O. Reg. 170/03 Provide details on the notices submitted in accordance with subsection 18(1) of the Safe Drinking-Water Act or section 16-4 of Schedule 16 of O.Reg.170/03 and reported to Spills Action Centre Incident Date Parameter Result Unit of Corrective Action Corrective Measure Action Date No adverse results during the 2012 reporting period. Adverse Water Quality Incidents for Regional locations not directly related to treated entry points (eg. Water Towers, Distribution Facilities etc.) can be located at www.region.waterloo.on.ca by referencing the Region of Waterloo 2011 Summary Report, Appendix B. Microbiological testing done under the Schedule 10, 11 or 12 of Regulation 170/03, during this reporting period. Number Range of E.Coli Range of Total Number Range of HPC of Or Fecal Coliform of HPC Results Samples Results Results Samples (min #)-(max #) (min #)-(max #) (min #)-(max #) Raw 159 All absent All absent Not required Treated53 All absent All absent 53 0 – 4 Distribution Two-tier system; distribution system operated by City of Kitchener Operational testing done under Schedule 7, 8 or 9 of Regulation 170/03 during the period covered by this Annual Report. Number of Range of Results NOTE : For continuous Grab (min #)-(max #) monitors use 8760 as the Samples number of samples. Turbidity (Raw)36 0.1 – 1.31 NTU Chlorine (Total)8760 0.78 – 2.23 Fluoride (If the DWS provides DWS does not provide fluoridation fluoridation) NOTEnot : Record the unit of measure if it is milligrams per litre. Summary of additional testing and sampling carried out in accordance with the requirement of an approval, order or other legal instrument. Date of legal Parameter Date Result Unit of Measure instrument issued Sampled Not applicable; no additional testing or sampling required. Summary of Inorganic parameters tested during this reporting period or the most recent sample results Parameter Sample Date Result Value Unit of Measure Exceedance Antimony 2/17/12 <0.6 mg/L No Arsenic 2/17/12 <1.0 ug/L No Barium 2/17/12 0.138 mg/L No Boron 2/17/12 0.05 mg/L No Cadmium 2/17/12 <0.1 ug/L No Chromium 2/17/12 0.002 mg/L No Mercury 2/17/12 <0.05 ug/L No Selenium 2/17/12 <5.0 ug/L No Drinking Water Systems Regulations Page 3of 6 (PIBS 4435e01) 3 - 43 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Sample Date Result Value Unit of Measure Exceedance Sodium 5/27/08 191 mg/L No* Uranium 2/17/12 <0.01 mg/L No Fluoride 7/09/12 0.14 mg/L No 2/17/12 <0.075 mg/L No <0.075 mg/L No 2/27/12 Nitrite 5/08/12 <0.075mg/L No 7/09/12 <0.075mg/L No 10/09/12 <0.075mg/L No 2/17/12 3.04 mg/L No 2/27/12 2.91 mg/L No Nitrate 5/08/12 2.99 mg/L No 7/09/12 3.07 mg/L No 10/09/12 2.92 mg/L No * There is no health related limit set for sodium, however, levels of greater than 20 mg/L are reported to the Health Department and the Ministry of Environment every five years. Summary of lead testing under Schedule 15.1 during this reporting period Range of Lead Number of Number of Location Type Results SamplesExceedances (min#) – (max #) Plumbing Two-tier system; distribution system operated by City of Kitchener Distribution Summary of Organic parameters sampled during this reporting period or the most recent sample results Parameter Sample Result Unit of Exceedance Date Value Measure Alachlor 2/17/12 <0.13 ug/L No Aldicarb 2/17/12 <0.5 ug/L No Aldrin + Dieldrin 2/17/12 <0.07 ug/L No Atrazine + N-dealkylated metobolites 2/17/12 <0.38 ug/L No Azinphos-methyl 2/17/12 <1.0 ug/L No Bendiocarb 2/17/12 <0.2 ug/L No Benzene 2/17/12 <0.5 ug/L No Benzo(a)pyrene 2/17/12 <0.01 ug/L No Bromoxynil 2/17/12 <0.05 ug/L No Carbaryl 2/17/12 <0.2 ug/L No Carbofuran 2/17/12 <0.2 ug/L No Carbon Tetrachloride 2/17/12 <0.5 ug/L No Chlordane (Total) 2/17/12 <0.39 ug/L No Chlorpyrifos 2/17/12 <0.25 ug/L No Cyanazine 2/17/12 <0.25 ug/L No Diazinon 2/17/12 <0.13 ug/L No Dicamba 2/17/12 <0.5 ug/L No 1,2-Dichlorobenzene 2/17/12 <0.5 ug/L No 1,4-Dichlorobenzene 2/17/12 <0.5 ug/L No Drinking Water Systems Regulations Page 4of 6 (PIBS 4435e01) 3 - 44 Drinking-Water Systems Regulation O. Reg. 170/03 Parameter Sample Result Unit of Exceedance Date Value Measure Dichlorodiphenyltrichloroethane (DDT) + 2/17/12 <0.78 ug/L No metabolites 1,2-Dichloroethane 2/17/12 <0.5 ug/L No 1,1-Dichloroethylene 2/17/12 <0.5 ug/L No (vinylidene chloride) Dichloromethane 2/17/12 <1.0 ug/L No 2-4 Dichlorophenol 2/17/12 <0.13 ug/L No 2,4-Dichlorophenoxy acetic acid (2,4-D) 2/17/12 <0.5 ug/L No Diclofop-methyl2/17/12 <0.5 ug/L No Dimethoate 2/17/12 <0.25 ug/L No Dinoseb 2/17/12 <0.5 ug/L No Diquat 2/17/12 <1.0 ug/L No Diuron 2/17/12 <0.6 ug/L No Glyphosate 2/17/12 <25 ug/L No Heptachlor + Heptachlor Epoxide 2/17/12 <0.26 ug/L No Lindane (Total) 2/17/12 <0.13 ug/L No Malathion 2/17/12 <0.13 ug/L No Methoxychlor 2/17/12 <0.13 ug/L No Metolachlor 2/17/12 <0.25 ug/L No Metribuzin 2/17/12 <0.13 ug/L No Monochlorobenzene 2/17/12 <0.5 ug/L No Paraquat 2/17/12 <1.0 ug/L No Parathion 2/17/12 <1.25 ug/L No Pentachlorophenol 2/17/12 <0.13 ug/L No Phorate 2/17/12 <0.25 ug/L No Picloram 2/17/12 <1.5 ug/L No Polychlorinated Biphenyls(PCB) 2/17/12 <0.25 ug/L No Prometryne 2/17/12 <0.25 ug/L No Simazine 2/17/12 <0.13 ug/L No THM Two-tier system; distribution system operated by City (:) NOTEshow latest annual averageof Kitchener Temephos 2/17/12 <2.5 ug/L No Terbufos 2/17/12 <0.25 ug/L No Tetrachloroethylene 2/17/12 <0.5 ug/L No 2,3,4,6-Tetrachlorophenol 2/17/12 <0.13 ug/L No Triallate 2/17/12 <0.2 ug/L No Trichloroethylene 2/17/12 0.6 ug/L No 2,4,6-Trichlorophenol 2/17/12 <0.13 ug/L No 2,4,5-Trichlorophenoxy acetic acid (2,4,5-T) 2/17/12 <0.5 ug/L No Trifluralin 2/17/12 <0.25 ug/L No Vinyl Chloride 2/17/12 <0.2 ug/L No Drinking Water Systems Regulations Page 5of 6 (PIBS 4435e01) 3 - 45 Drinking-Water Systems Regulation O. Reg. 170/03 List any Inorganic or Organic parameter(s) that exceeded half the standard prescribed in Schedule 2 of Ontario Drinking Water Quality Standards. Parameter Result Value Unit of Measure Date of Sample Chloramines 1.54 mg/L 1/16/12 Chloramines 1.52 mg/L 1/23/12 Chloramines 1.56 mg/L 2/13/12 Chloramines 1.56 mg/L 2/21/12 Chloramines 1.56 mg/L 2/27/12 Chloramines 1.54 mg/L 3/06/12 Chloramines 1.51 mg/L 3/12/12 Chloramines 1.51 mg/L 3/13/12 Chloramines 1.58 mg/L 3/19/12 Chloramines 1.65 mg/L 4/02/12 Chloramines 1.55 mg/L 4/11/12 Chloramines 1.59 mg/L 4/16/12 Chloramines 1.53 mg/L 4/30/12 Chloramines 1.55 mg/L 5/23/12 Chloramines1.56 mg/L 7/03/12 Chloramines1.64 mg/L 7/09/12 Chloramines1.54 mg/L 7/23/12 Chloramines1.51 mg/L 8/20/12 Chloramines1.82 mg/L 9/17/12 Chloramines1.65 mg/L 9/24/12 Chloramines1.65 mg/L 10/01/12 Chloramines1.51 mg/L 10/15/12 Chloramines1.53 mg/L 11/05/12 Chloramines1.57 mg/L 11/26/12 Chloramines1.56 mg/L 12/03/12 Chloramines1.65 mg/L 12/11/12 Chloramines1.51 mg/L 12/24/12 Drinking Water Systems Regulations Page 6of 6 (PIBS 4435e01) 3 - 46